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In 1868, Elizabeth became engaged to George DeWalt Harter, the son of well-established Canton banker Isaac Harter Senior, and a banker himself. George was also the first plant manager of Cornelius Aultman’s Mansfield factory. In March 1869, the two married and Elizabeth Aultman became Elizabeth Harter. In January 1870, the two had their first child, Eliza, named after Elizabeth’s mother. The newlywed couple was wrought with grief when their daughter passed away at only six months old. Over the next seventeen years, Elizabeth and George had five more children, consisting of four girls and one boy. Their only son, Cornelius Aultman Harter, passed when he was only four years old on May 17, 1880. On December 8, 1890, George Harter’s death made Elizabeth the sole parent of four daughters, aged 19, 12, 10, and 3. In addition to her professional responsibilities with inheriting her late husband’s business interests, Elizabeth now had to raise four young women on her own.